Search results for "Methyl benzene"

showing 2 items of 2 documents

3,5-Bis(trifluoromethyl)phenyl 4-methylbenzenesulfonate

2017

Molecules of the title compound, C15H10F6O3S, are composed of 3,5-bis(trifluoromethyl)phenyl substituted with a toluene-4-sulfonate group. The dihedral angle between two aromatic moieties is 45.10 (5)°. In the crystal, molecules are connected by weak C—H...O and C—H...F contacts. One of the trifluoromethyl groups is disordered.

crystal structure010405 organic chemistryMeth-Crystal structuretosyl­atesDihedral angle010402 general chemistry01 natural sciencesCoupling reaction0104 chemical sciencesCrystalchemistry.chemical_compoundSulfonatecross-coupling reactionschemistryGroup (periodic table)Polymer chemistryMethyl benzeneIUCrData
researchProduct

N-[(1S,2S)-2-Amino-1,2-diphenyl­eth­yl]-4-methyl­benzene­sulfonamide [(S,S)-TsDPEN]

2010

The crystal structure of the title compound, C21H22N2O2S, shows a network of N—H...N and N—H...O hydrogen bonds. The tolyl and 1-phenyl rings are almost mutually coplanar [7.89 (9)°], while the 2-phenyl ring makes a dihedral angle of 50.8 (1) ° with the 1-phenyl ring. An intramolecular N—H...N hydrogen bond stabilizes the molecular conformation.

chemistry.chemical_classificationHydrogen bondGeneral ChemistryCrystal structureDihedral angleCondensed Matter PhysicsRing (chemistry)BioinformaticsMedicinal chemistryOrganic PapersSulfonamidelcsh:Chemistrylcsh:QD1-999chemistryMethyl benzeneGeneral Materials ScienceActa Crystallographica Section E: Structure Reports Online
researchProduct